Effect of Surface Roughness on Dyne Testing

Question: We have a customer that uses your test markers to measure the surface energy of aluminum before bonding it to a composite. They find the test works great on a smooth surface, but on rougher surfaces they are unsure of results, and don’t think they are accurate. Is there a rule of thumb on how smooth a surface needs to be for surface energy testing?

Answer: I don’t know that you could really come up with a “rule” as far as roughness goes, but there is an obvious problem with textured surfaces: the test fluid will tend to settle into the “valleys” so wetting vs. beading will become more and more difficult to gauge as the roughness increases. This will be as true for plastics, composites, glass, and other materials as it is for metals. It’s important to keep in mind that the dyne test is based on the behavior of a retreating liquid/solid contact line. When this line is on anything other than a horizontal plane, gravity comes into play, either aiding or abetting the retreat of the liquid.

One thing is certain – the testing of this material should be done with bottled test fluids, applied as lightly as possible (in terms of both amount of fluid used and pressure applied) with a cotton swab. Test markers really will not be controllable enough, and will tend to flood the valleys with test fluid. Also, as testing of metals is usually performed to evaluate surface cleanliness, test markers are not a good option, as surface contaminants can affect results (for details on this, please see our discussion here).

Using a strong magnifier will be helpful – I’d look for signs that the fluid is creeping away from even the valleys, and tending to aggregate in micro-puddles rather than coating the entire low area. This discernment may be easiest at the perimeter of the test area. Also, while it may be rather interpretive rather than an absolute indicator, if the high spots on the surface retain a thin film of test fluid, that is a strong suggestion that wetting has been achieved.

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Russ Smith

Russ Smith formed Diversified Enterprises - the first business to focus specifically on applications of the dyne test - in 1986, and has served as President of the company ever since. He has over 30 years of experience in the fields of surface treatment and analysis, and deals with technical inquiries from customers worldwide on a daily basis. Russ is a member of ASTM, the Society of Plastics Engineers, the American Chemical Society, the American Society for Quality, the American Association for the Advancement of Science, and TAPPI.

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